Analysis for Optimum Conditions for Recovery of Valuable Metals from E-waste Through Black Copper Smelting

فصل «Analysis for Optimum Conditions for Recovery of Valuable Metals from E-waste Through Black Copper Smelting» از کتاب «The Minerals, Metals & Materials Series» بر «ذوب مس» در حوزه «متالورژی مس» تمرکز دارد. محتوا مبانی علمی، روش‌های فنی و پیامدهای عملی موضوع را به‌صورت منسجم توضیح می‌دهد. برای انتخاب فرایند، طراحی واحد، تحلیل بهره‌برداری و رفع عیب در استخراج و پالایش مس مفید است.

One of the processing routes for extracting valuable metals from e-waste is through the black copper smelting. However, the underlying knowledge of the thermodynamics behaviour of the valuable metals contained in e-waste during smelting are limited which prevent us from developing an optimised process to recover all the metals. To illustrate this, the distribution behaviour of germanium (Ge) and palladium (Pd) between liquid copper and ferrous-calcium-silicate slag during black copper smelting was analysed. It was demonstrated that oxygen partial pressure and slag composition affect the partitioning of these metals to the copper phase and the favourable slag chemistry for recovering these metals is opposing.